The effect of wheat straw bleaching on some mechanical properties of wheat straw/LDPE biocomposites

Document Type : Original research

Authors

Food Engineering and Post-harvest Technology Research Department, Agricultural Engineering Research Institute (AERI), Agricultural Research, Education and Extension Organization (AREEO), Karaj, Iran

Abstract

Using biocomposites containing wheat straw (WS) and synthetic polymers like polyethylene (PE) has gained tremendous popularity, but its application in the packaging industry is not substantial. Due to the prevalence of raw WS color which manifests itself in the WS/LDPE biocomposite, the present investigation is dedicated to fabricate a bleached WS/LDPE composite. Thus, raw WS and the pulp of WS were treated with three levels of xylanase, five concentrations of hydrogen peroxide and five levels of sodium dithionite. The bleached raw WS and its pulp were used to fabricate WS/LDPE composites and their colorimetric properties were measured using L*, a*, and b* coordinates. The results indicated that "bleached raw WS with 4% H2O2" and "bleached WS pulp with 10 units of xylanase and by addition of 1% H2O2" demonstrate the highest degree of lightness based on L* value. Then, 40% of above mentioned treatments were blended with LDPE to develop a biocomposite using a twin screw extruder. Further, lightness index and the mechanical properties of the final composites were measured. Results indicated that the composites containing unbleached raw WS had the lowest and the bleached WS pulp with 10 unites of xylanase and 1% H2O2 had the highest L value amongst all treatments. Also the raw WS/LDPE and the bleached raw WS/LDPE composites had the highest and the lowest tensile strength, respectively. It needs to be mentioned that the flexural strength of all treatments was higher than the control, whereas the impact resistance of them was lower than the control.

Keywords

Alemdar, A. & Sain, M. (2008). Biocomposites from wheat straw nanofibres: morfology, thermal and mechanical properties. Composites Science and Technology, 68(2), 557-565.
Ansari, H. (2012). Investigation of different bleaching methods of wheat straw-LDPE composite in order to apply in food packaging. Msc. Thesis, University of Tehran, Faculty of Agricultural Science & Engineering, Food Science Engineering Department. (In Persian) 
ASTM D638. (2005). Standard test method for tensile properties of plastics.
ASTM D256. (2005). Standard test methods for determining the izod pendulum impact resistance of plastics.
ASTM D790. (2005). Standard test methods for flexural properties of unreinforced and reinforced plastics and electrical insulating materials.
Bajpai, P. (2012). Biotechnology for pulp and paper processing. Springer Science + Business Media, LLC.
Clemons, C. (2002). Wood Plastic Composites in theUSA. Forest Products Journal, 52(6), 10-18.
DeArmitt, C. (2011). Functional fillers for plastics, in Applied plastics engineering handbook (Kutz M, Ed.), 455-468, Elsevier.
Ghosh, U.K. (2006). Short sequence environment friendly bleaching of wheat straw pulp. Journal of scientific and industrial research, 65(1), 68-71.
Gorjani, F., & Omidvar, A. (2006). Investigation on manufacturing process and mechanical properties wheat straw/recycled polyethylene composite. Pajouhesh-va-Sazandegi, 72, 84-88.
Hejazi, S., Jahan Latibari A., Patt, R., Kordsachia, O., Parsapazhouh, D., Tschirner U. (2007). Investigation on tcf bleaching of wheat straw soda pulp. Iranian Journal of Natural Resources, 59(4), 935- 951.
Khatibi, R. (2009). Investigate of mechanical & physical properties of wood plastic composite based on HDPE and cornstalk flours. Msc. Thesis, Islamic Azad University, Science & Research Unit, Tehran.
Klyosov, A.A. (2007). Wood Plastic Composites, Willey, London.
Mohammed, L., Ansari, M.N.M., Pua, G., Jawaid, M., & Saiful Islam, M. (2015). A review on natural fiber reinforced polymer composite and its applications. International Journal of Polymer Science, 15 pages.
Mohanty, A.K., Misra, M., Drzal, L.T., Selke, S.E., Harte, B.R., & Hinrichsen, G. (2005). Natural fibers, biopolymers, and biocomposites: an introduction, in natural fibers, biopolymers, and biocomposites (Mohanty AK et al., Eds.), pp. 1- 36, CRC Press.
Nishino, T. (2004). Natural fiber sources, in green composites, polymer composites and the environment, (Baillie C, Ed.), pp. 49-80, CRC Press.
Pappua, A., Patil, V., Jain, S., Mahindrakar, A., Haquea, R., & Thakur, V.K. (2015). Advances in industrial prospective of cellulosic macromolecules enriched banana biofibre resources: A review. International Journal of Biological Macromolecules, 79, 449–458.
Pappua, A., Saxena, M., Kumar Thakur, V., Sharma, A., & Haque, R. (2016). Facile extraction, processing and characterization of biorenewable sisal fibers for multifunctional applications.Journal of Macromolecular Science, Part A. Pure and Applied Chemistry, 53(7), 424-432.
Raschip, I.E., Dumitriu, R.P., Grigoras, V.C., Cazacu, G., & Vasile, C. (2006). On the compatibility of the hydroxypropylcellulose/epoxy modified lignin blends, in New trends in natural and synthetic polymer science (Vasile C, Zaikov GE, Eds.), pp. 69-90, Nova Science Publishers.
Sain, M., & Panthapulakkal, S. (2006). Bioprocess preparation of wheat straw fibers and their characterization. Industrial Crops and Products, 23(1), pp.1-8.
Selke, S.E. (2000). Plastics recycling and biodegradable plastics, in modern plastics handbook (Harper CA, Ed.), 12.11- 12.108, McGraw - Hill.
Sun, R.C., & Tomkinson, T. (2000). Essential guides for isolation/purification of polysaccharides, in Encyclopedia of Separation Science (Wilson ID, Adlard TR, Poole CF, Cook M, Eds.), pp. 4568-4574, Academic Press, London.
Tajeddin, B. (2014). Cellulose-based polymers for packaging applications, in Lignocellulosic polymer composites (Kumar Thakur V, Ed.), pp. 477-498, Scrivener Publishing LLC.
Tajeddin, B. (2015). The comparison of MAPE and PEG effects on the mechanical characteristics of wheat straw/LDPE biocomposites for packaging application. Polymers & Polymer Composites, 23(9), 589-594.
Tajeddin, B., & Ansari, H. (2016). Thermal and colorimetric properties of bleached wheat straw/LDPE biocomposites. Iranian Journal of Wood and Paper industries, 7(2), 283- 295.
Tajeddin, B., Russly, A.R., & Chuah, A.L. (2010). The effect of polyethylene glycol on the characteristics of kenaf cellulose- low density polyethylene biocomposites. International Journal of Biological Macromolecules, 47, 292-297.
Veisi, A., & Mahdavi, S. (2016). Mixing bleached white poplar and wheat straw chemimechanical pulps to improve the mechanical and optical characteristics. Bioresources, 11(2), 2987-2997.
Ward, I.M., & Sweeney, J.  (2004). An introduction to the mechanical properties of solid polymers, John Wiley & Sons, Ltd.
Yu, L., Dean, K., & Li, L. (2006). Polymer blends and composites from renewable resources. Progress in Polymer Science, 31, 576-602.
Zhao, J., Li, X.Z., & Qu, Y.B. (2005). Application of enzymes in producing bleached pulp from wheat straw. Bioresource Technology, 97, 1470–1476.